Two Dimensional Silicides/Germanides

Novel, interesting structures formed at monolayer rare earth coverage on the Si(111) and Ge(111) surfaces.

Two Dimensional Silicides

Rare Earth (RE) metals have been found to form a number of novel structures on silicon, depending on the substrate orientation and preparation conditions. One of the more interesting structures is that formed at monolayer (ML) coverages on the Si(111) surface, so called "two dimensional" (2D) silicides. This silicide is known to form for most of the trivalent rare earth metals. A very similar structure is also formed under similar conditions on the Ge(111) surface, though this has not been as thoroughly investigated. The 2D silicide may be of technological interest. Unusually low Schottky barrier heights of 0.2–0.3 eV have been recorded for RE silicide on n-type Si. The novel structure may also have interesting magnetic properties, and could form a useful template for further growth.

The 2D silicide is formed when 1 ML of RE metal (e.g. Er, Ho, Tm) is deposited onto the clean 7 × 7 reconstruction of Si(111) and subsequently annealed to around 500 °C. The anneal causes the surface to reconstruct and a novel interface structure is formed. A single atomic layer of rare earth metal is located above the Si substrate in so called T4, three fold hollow sites. Above the RE the silicide is terminated by a bulk like silicon bilayer, the orientation of which is rotated by 180° with respect to the substrate. The structure is shown schematically in Figure 1.

Schematic diagram of the 2D silicides. A single RE layer sits beneath a reverse buckled bulk like Si bilayer

Figure 1: Schematic diagram of the 2D silicides

These 2D silicides have been extensively studied using a variety of techniques. The York SPG have used MEIS, LEED and STM to investigate their properties (see further reading). It has also been seen that similar structures will form using Ge(111). Although not as many examples are known it is expected that such 2D germanides will form for all the trivalent REs, as for the silicides.

Further Reading

A number of papers have been published on rare earth silicides, both by the York group and others. A selection of references is given here.

  1. D. J. Spence, S. P. Tear, T. C. Q. Noakes, and P. Bailey, "Medium-energy ion scattering studies of two-dimensional rare-earth silicides", Phys. Rev. B, 61 5707 (2000)
  2. H. Kitayama, S. P. Tear, D. J. Spence, and T. Urano, "Structural analysis of two-dimensional Holmium silicide by low energy electron diffraction", Surf. Sci., 482–485 1481 (2001)
  3. M. Lohmeier, W. J. Huisman, G. ter Horst, P. M. Zagwijn, E. Vlieg, C. L. Nicklin, and T. S. Turner, "Atomic structure and thermal stability of two-dimensional Er silicide on Si(111)", Phys. Rev. B, 54 2004 (1996)
  4. P. Wetzel, C. Pirri, P. Paki, D. Bolmont, and G. Gewinner, "Structure of a two-dimensional epitaxial Er silicide on Si(111) investigated by Auger-electron diffraction", Phys. Rev. B 47 3677 (1993)
  5. C. Bonet, D. J. Spence, and S. P. Tear, "Structural study of 2D dysprosium germanide and silicide by means of quantitative LEED I-V analysis", Surf. Sci., 504 183 (2002)